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RAS PresidiumДоклады Российской академии наук. Химия, науки о материалах Doklady Chemistry

  • ISSN (Print) 2686-9535
  • ISSN (Online) 3034-5111

SINGLE-, DOUBLE- AND MULTI-WALLED CARBON NANOTUBES AS ELECTRICALLY CONDUCTIVE ADDITIVES IN LITHIUM-ION BATTERY CATHODES

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PII
10.31857/S268695352260074X-1
DOI
10.31857/S268695352260074X
Publication type
Status
Published
Authors
A. V. Babkin
  • Affiliation: Department of Chemistry, Lomonosov Moscow State University
A. V. Kubarkov
  • Affiliation:
    Department of Chemistry, Lomonosov Moscow State University
    Skolkovo Institute of Science and Technology
Volume/ Edition
Volume 508 / Issue number 1
Pages
26-34
Abstract
The paper presents a comparative study of the characteristics of lithium iron phosphate positive electrodes with various types of commercially available carbon nanotubes – single-walled (SWCNT), double-walled (DWCNT) and multi-walled (MWCNT). Electrochemical characteristics of the cathode materials were investigated using electrochemical impedance spectroscopy and galvanostatic charge/discharge measurements. Cyclic stability at various current densities was estimated. The best electrochemical characteristics are exhibited by cathode materials with SWCNT (advantage over DWCNT at discharge rates higher than 10C) and DWCNT (advantage over SWCNT during prolonged cycling). During cycling at a current density of 1C, the greatest loss of capacity was demonstrated by the MWCNT-based electrode. At the same time, the electrodes with SWCNT and DWCNT demonstrated satisfactory capacity retention after 50 charge/discharge cycles: over 94 and over 98%, respectively.
Keywords
литий-ионный аккумулятор проводящая добавка углеродные нанотрубки электропроводность
Date of publication
18.09.2025
Year of publication
2025
Number of purchasers
0
Views
5

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