RAS PresidiumДоклады Российской академии наук. Химия, науки о материалах Doklady Chemistry

  • ISSN (Print) 2686-9535
  • ISSN (Online) 3034-5111

SYNTHESIS AND STRUCTURE OF NEW [5]FERROCENOPHANE

PII
10.31857/S2686953523600095-1
DOI
10.31857/S2686953523600095
Publication type
Status
Published
Authors
Volume/ Edition
Volume 513 / Issue number 1
Pages
62-66
Abstract
The first example of intramolecular diastereoselective domino reaction of ferrocene 1,1'-bis-enone to [5]ferrocenophane initiated with sodium ethylate was found. The product is [5]ferrocenophane with two pyridyl and one ethoxy substituents arranged asymmetrically in five carbon bridge. Diffraction studies showed that ferrocene is in almost ideal eclipsed conformation. The fan conformation found in the crystal is also preserved in solution, which was determined by NMR spectroscopy.
Keywords
ферроценофан халкон домино-реакция
Date of publication
18.09.2025
Year of publication
2025
Number of purchasers
0
Views
5

References

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