- PII
- 10.31857/S2686953523600228-1
- DOI
- 10.31857/S2686953523600228
- Publication type
- Status
- Published
- Authors
- Volume/ Edition
- Volume 513 / Issue number 1
- Pages
- 93-99
- Abstract
- The paper presents a new low-temperature method for the synthesis of highly dispersed powders of double phosphates LiCoPO4 and LiNiPO4 using low-waste technology. It has been shown that the morphology and particle size of the obtained materials depend on the type of initial precursors. The obtained compounds are characterized by elemental, XRD, SEM, cyclic volammetry, cyclic chronopotentiometry analyses. A new approach to the synthesis of submicron powders of lithium double phosphates and transition metal (nickel, cobalt) is more effective compared to current methods.
- Keywords
- синтез двойные фосфаты катод электродные материалы электрохимические свойства
- Date of publication
- 18.09.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 6
References
- 1. Kraytsberg A., Ein-Eli Y. // Adv. Energy Mater. 2012. V. 2. № 8. P. 922–939. https://doi.org/10.1002/aenm.201200068
- 2. Song S., Peng X., Huang K., Zhang H., Wu F., Xiang Y., Zhang X. // Nanoscale Res. Lett. 2020. V. 15. P. 110. https://doi.org/10.1186/s11671-020-03335-8
- 3. Кулова Т.Л. // Электрохимия. 2013. Т. 49. № 1. С. 3–28. https://doi.org/10.7868/S0424857013010118
- 4. Örnek A. // J. Colloid Interface Sci. 2017. V. 504. P. 468–478. https://doi.org/10.1016/j.jcis.2017.05.118
- 5. Tolganbek N., Yerkinbekova Y., Kalybekkyzy S., Bake-nov Zh., Mentbayeva A. // J. Alloys Compd. 2021.V. 882. P. 160774. https://doi.org/10.1016/j.jallcom.2021.160774
- 6. Cheng Q., Zhao X., Yang G., Mao L., Liao F., Chen L., He P., Pan D., Chen Sh. // Energy Stor. Mater. 2021. V. 41. P. 842–882. https://doi.org/10.1016/j.ensm.2021.07.017
- 7. Kosova N.V., Podgornova O.A., Devyatkina E.T., Podugolnikov V.R., Petrov S.A. // J. Mater. Chem. A. 2014. V. 2. P. 20697–20705. https://doi.org/10.1039/C4TA04221B
- 8. Herle P., Ellis B., Coombs N., Nazar L.F. // Nat. Mater. 2004. V. 3. № 3. P. 147–152. https://doi.org/10.1038/nmat1063
- 9. Biendicho J.J., West A.R. // Solid State Ion. 2011. V. 203. № 1. P. 33–36. https://doi.org/10.1016/j.ssi.2011.08.006
- 10. Truong Q.D., Devaraju M.K., Tomai T., Honma I. // ACS Appl. Mater. Interfaces. 2013. V. 5. № 20. P. 9926–9932. https://doi.org/10.1021/am403018n
- 11. Kempaiah Devaraju M., Duc Truong Q., Hyodo H., Sasaki Y., Honma I. // Sci. Rep. 2015. V. 5. P. 11041. https://doi.org/10.1038/srep11041
- 12. Pourhakkak P., Taghizadeh A., Taghizadeh M., Ghaedi M., Haghdoust S. // Interface Sci. Technol. 2021. V. 33. P. 1–70. https://doi.org/10.1016/B978-0-12-818805-7.00001-1
- 13. Li Z., Peng Z., Zhang H., Hu T., Hu M., Zhu K., Wang X. // Nano Lett. 2016. V. 16. №. 1. P. 795–799. https://doi.org/10.1021/acs.nanolett.5b04855
- 14. Ludwig J., Nilges T. // J. Power Sources. 2018. V. 382. P. 101–115. https://doi.org/10.1016/j.jpowsour.2018.02.038
- 15. Karafiludis S., Buzanich A.G., Heinekamp C., Zimathies A., Smales J.G., Hodoroaba V.-D., ten Elshof J.E., Emmerling F., Stawski T.M. // Nanoscale. 2023. V. 15. № 8. P. 3952–3966. https://doi.org/10.1039/D2NR05630E
- 16. Zhang M., Garcia-Araez N., Hector A. L. // J. Mater. Chem. A. 2018. V.6 № 30. P. 14483–14517. https://doi.org/10.1039/C8TA04063J
- 17. Sreedeep S., Natarajan S., Aravindan V. // Curr. Opin. Electrochem. 2022. V. 31. P. 100868. https://doi.org/10.1016/j.coelec.2021.100868
- 18. Markevich E., Sharabi R., Gottlieb H., Borgel V., Fridman K., Salitra G., Aurbach D., Semrau G., Schmidt M.A., Schall N., Bruenig C. // Electrochem. Commun. 2012. V. 15. № 1. P. 22–25. https://doi.org/10.1016/j.elecom.2011.11.014
- 19. Маслова М.В., Жаров Н.В., Иваненко В.И. Способ получения двойного ортофосфата лития и переходного металла. Патент RU 2022 120 287 A от 01.03.2023 г.
