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RAS PresidiumДоклады Российской академии наук. Химия, науки о материалах Doklady Chemistry

  • ISSN (Print) 2686-9535
  • ISSN (Online) 3034-5111

Selective hydrogenation of carvone on Pd/Al2O3 under mild reaction conditions

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PII
S3034511125010026-1
DOI
10.7868/S3034511125010026
Publication type
Article
Status
Published
Authors
T. Yu. Osadchaya
  • Occupation: Institute of Mechanical, Process and Energy Engineering (IMPEE), School of Engineering and Physical Sciences (EPS)
  • Affiliation: Heriot-Watt University
Volume/ Edition
Volume 520 / Issue number 1
Pages
12-22
Abstract
Liquid-phase hydrogenation of carvone to carveol using Pd/Al2O3 catalyst under mild reaction conditions was studied. Carvone having three different functional groups, is a complex object for selective hydrogenation, since endo- and exo- >C=C< bonds and carbonyl group have different reactivity. The aim of the study was to increase the selectivity for carveol, an important industrial product in the food, perfumery and pharmaceutical industries. Optimum conditions for carvone hydrogenation to carveol were established: toluene solvent, Pd/Al2O3 catalyst and temperatures ≥323 K. It was shown that the selectivity for carveol under mild conditions reaches 20%. The results demonstrate the potential of using Pd/Al2O3 for efficient and selective hydrogenation of carvone in industry. This study can form the basis for the development of new technologies for the production of carveol with high selectivity and yield, which is important for improving the efficiency and sustainability of chemical processes in various industries.
Keywords
каталитическая активность селективность нанесенные палладиевые катализаторы карвон карвакрол карвоментон карватанацетон карвеол
Date of publication
18.09.2025
Year of publication
2025
Number of purchasers
0
Views
8

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