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RAS PresidiumДоклады Российской академии наук. Химия, науки о материалах Doklady Chemistry

  • ISSN (Print) 2686-9535
  • ISSN (Online) 3034-5111

Oxygen exchange and mechanism of oxygen intake by complex oxides with a swedenborgite structure

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PII
S3034511125010036-1
DOI
10.7868/S3034511125010036
Publication type
Article
Status
Published
Authors
D. I. Turkin
  • Occupation: Academician of the RAS
  • Affiliation: Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences
Volume/ Edition
Volume 520 / Issue number 1
Pages
23-32
Abstract
The kinetics of oxygen sorption from air by Y0.8Ca0.2BaCo4-xFexO7+δ (x = 0, 1) is studied by nonisothermal thermogravimetric measurements. The activation energy is calculated by model-free methods of Friedman, Starink and Vyazovkin. The master plot and Coates–Redfern methods are applied to determine the mechanism of oxygen intake. The results show the activation energies and frequency factors are 189 and 197 kJ mol–1 and 4.7 × 1013 and 2.3 × 1014 min–1 in Y0.8Ca0.2BaCo4O7+δ and Y0.8Ca0.2BaCo3FeO7+δ, respectively. The arguments are given in proof of oxygen sorption determined by the volume random nucleation and growth of the oxygen-rich nuclei.
Keywords
кобальтиты кислородный обмен кинетический анализ
Date of publication
18.09.2025
Year of publication
2025
Number of purchasers
0
Views
8

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