- PII
- S3034511125050012-1
- DOI
- 10.7868/S3034511125050012
- Publication type
- Review
- Status
- Published
- Authors
- Volume/ Edition
- Volume 524 / Issue number 1
- Pages
- 3-9
- Abstract
- This review summarizes the results of the authors' study of chemical transformations of basic N-substituted methyl -thieno[3,2-]pyrrolecarboxylate in two main directions concerning the synthesis of new polymers and heterocycles (isoquinolines). In the first part presents data on the synthesis of a series of polyheterofunctionalized polymers based on the first developed from monomeric starting 4N-substituted bis-4-thieno[3,2-]-pyrrolomethanes and structurally similar products of cross-coupling (1-pyrrol-3-ylmethyl)-4-thieno[3,2-]-pyrroles, their physicochemical properties were studied, possible step-by-step routes of formation and examples of practical use were proposed. In the second part the results obtained in the course of studying the AlCl-promoted acylation reactions of -benzyl- and -2,3-dimethoxybenzyl-substituted methyl 4-thieno[3,2-]-pyrrole carboxylates with acid chlorides of the above-mentioned acids with the isolation of a new topology isoquinolines fused with 4H-thieno[3,2-]pyrrole and benzene rings are discussed.
- Keywords
- N-бензилпроизводные метил-4H-тиено[3,2-b]пирролкарбоксилата бис-4H-тиено[3,2-b]пирроломеганы (1H-пиррол-3-илметил)-4H-тиено[3,2-b]пирролы бром окислительная полимеризация полимеры хлорангидриды замещенных 4H-тиено[3,2-b]пирролкарбоновых кислот хлорид алюминия циклизация изохинолины
- Date of publication
- 01.01.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 54
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