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RAS PresidiumДоклады Российской академии наук. Химия, науки о материалах Doklady Chemistry

  • ISSN (Print) 2686-9535
  • ISSN (Online) 3034-5111

MECHANOLUMINESCENT AND MECHANOCHEMICAL PROCESSES IN THE CpZrCl–ORGANOALUMINUM COMPOUNDS SYSTEM

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PII
S3034511125060063-1
DOI
10.7868/S3034511125060063
Publication type
Article
Status
Published
Authors
N.A. Panova
  • Occupation: Graduate student, High-energy Chemistry and Catalysis Lab.
  • Affiliation: Institute of Petrochemistry and Catalysis UFRC, Russian Academy of Sciences
P.V. Kovyazin
  • Occupation: PhD, Senior Researcher, Laboratory of Structural Chemistry
  • Affiliation: Institute of Petrochemistry and Catalysis UFRC, Russian Academy of Sciences
L.V. Parfenova
  • Occupation: PhD, Head of Laboratory, Organic Synthesis Lab
  • Affiliation: Institute of Petrochemistry and Catalysis UFRC, Russian Academy of Sciences
G.L. Sharipov
  • Occupation: PhD, Head of Laboratory, Organic Synthesis Lab
  • Affiliation: Institute of Petrochemistry and Catalysis UFRC, Russian Academy of Sciences
A.A. Tukhbatullin
  • Occupation: PhD, Senior Researcher, High-energy Chemistry and Catalysis Lab.
  • Affiliation: Institute of Petrochemistry and Catalysis UFRC, Russian Academy of Sciences
Volume/ Edition
Volume 525 / Issue number 1
Pages
72-80
Abstract
The photo- and mechanoluminescent characteristics of catalytic systems comprising zirconocene dichloride and organoaluminum compounds (AOC) was study. It was found that the addition of AlBu to CpZrCl leads to the appearance of additional luminescence bands, which indicates the formation of light-emitting products of mechanochemical reactions. Intense sonotriboluminescence was detected during ultrasonic treatment of a suspension of CpZrCl crystals in hexane. Ultrasound generates cavitation shock waves that accelerate and collide suspension microcrystals, causing their destruction, as well as local electrification with microdischarges and subsequent luminescence. The development of research in the field of mechanochemical transformations during mechanical action in heterogeneous systems with accompanying sonotriboluminescence can lay the foundation for the creation of new methods of luminescent control over the course of catalytic processes involving metal complexes and AOC.
Keywords
цирконоцендихлорид алюминийорганические соединения механохимия механолюминесценция ультразвук
Date of publication
01.01.2026
Year of publication
2026
Number of purchasers
0
Views
46

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