RAS PresidiumДоклады Российской академии наук. Химия, науки о материалах Doklady Chemistry

  • ISSN (Print) 2686-9535
  • ISSN (Online) 3034-5111

MIXED-LIGAND ANIONIC Pd COMPLEXES IN THE FORMATION OF BICYCLO[2.2.1]HEPTANE DERIVATIVES FROM NORBORNENE

PII
S3034511125060078-1
DOI
10.7868/S3034511125060078
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 525 / Issue number 1
Pages
81-92
Abstract
The results of the kinetic studies of the influence of reaction system components on the composition of truly active Pd complexes participating in the formation of bicyclo[2.2.1]heptane derivatives as a result of three-component coupling of aryl halide, norbornene, and aryl acetylene are discussed. Based on the data on the sensitivity of differential selectivity of conjugation nodes of competing catalytic cycles of the reaction under consideration the anionic character and mixed-ligand composition of catalytically active Pd compounds have been established.
Keywords
норборнен производные бицикло[2.2.1]гептана катализ палладий кинетика дифференциальная селективность
Date of publication
01.01.2026
Year of publication
2026
Number of purchasers
0
Views
44

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