- PII
- 10.31857/S2686953523600162-1
- DOI
- 10.31857/S2686953523600162
- Publication type
- Status
- Published
- Authors
- Volume/ Edition
- Volume 509 / Issue number 1
- Pages
- 22-29
- Abstract
- In the course of the synthesis of oligosaccharides related to fragments of the capsular polysaccharide of Haemophilus influenzae type e, the transformations of various 2-O-trifluoromethanesulfonate derivatives of β-D-glucopyranosides in reactions with an azide anion was studied. It gives the products of both nucleophilic substitution and a rearrangement of the 6-membered pyranose ring with its contraction to the 5-membered one through (О-5–С-2)-cyclization. Their formation was interpreted for the first time using quantum mechanical calculations.
- Keywords
- метод функционала плотности нуклеофильное замещение сужение цикла переходные состояния
- Date of publication
- 18.09.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 5
References
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