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RAS PresidiumДоклады Российской академии наук. Химия, науки о материалах Doklady Chemistry

  • ISSN (Print) 2686-9535
  • ISSN (Online) 3034-5111

COMPOSITE MATERIALS BASED ON MOF ZIF-8 AND IONIC LIQUID [BMIm]+[BF4]−: AN EPR STUDY USING NITROXIDE SPIN PROBES

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PII
10.31857/S2686953523700206-1
DOI
10.31857/S2686953523700206
Publication type
Status
Published
Authors
N. А. Kudryavyh
  • Affiliation: International Tomography Center, Siberian Branch of the Russian Academy of Sciences
Volume/ Edition
Volume 509 / Issue number 1
Pages
61-68
Abstract
A method for the controlled filling of pores in metal-organic frameworks (MOFs) with ionic liquids (ILs) is proposed, which can be applied for selective gas sorption in MOFs. Using an example of MOF ZIF-8 and IL [BMIm]+[BF4]−, the composites with different IL content were prepared upon control by electron paramagnetic resonance (EPR) of nitroxide spin probes. The effect of IL on the sorption of nitric oxide (II) into these composites was studied using inversion gas chromatography.
Keywords
нитроксильные радикалы металл-органические координационные полимеры (МОКП) ZIF-8 NO ионные жидкости ЭПР
Date of publication
18.09.2025
Year of publication
2025
Number of purchasers
0
Views
7

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