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RAS PresidiumДоклады Российской академии наук. Химия, науки о материалах Doklady Chemistry

  • ISSN (Print) 2686-9535
  • ISSN (Online) 3034-5111

Selective hydrogenation of carvone on Pd/Al2O3 under mild reaction conditions

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PII
S3034511125010026-1
DOI
10.7868/S3034511125010026
Publication type
Article
Status
Published
Authors
T. Yu. Osadchaya
  • Occupation: Institute of Mechanical, Process and Energy Engineering (IMPEE), School of Engineering and Physical Sciences (EPS)
  • Affiliation: Heriot-Watt University
Volume/ Edition
Volume 520 / Issue number 1
Pages
12-22
Abstract
Liquid-phase hydrogenation of carvone to carveol using Pd/Al2O3 catalyst under mild reaction conditions was studied. Carvone having three different functional groups, is a complex object for selective hydrogenation, since endo- and exo- >C=C< bonds and carbonyl group have different reactivity. The aim of the study was to increase the selectivity for carveol, an important industrial product in the food, perfumery and pharmaceutical industries. Optimum conditions for carvone hydrogenation to carveol were established: toluene solvent, Pd/Al2O3 catalyst and temperatures ≥323 K. It was shown that the selectivity for carveol under mild conditions reaches 20%. The results demonstrate the potential of using Pd/Al2O3 for efficient and selective hydrogenation of carvone in industry. This study can form the basis for the development of new technologies for the production of carveol with high selectivity and yield, which is important for improving the efficiency and sustainability of chemical processes in various industries.
Keywords
каталитическая активность селективность нанесенные палладиевые катализаторы карвон карвакрол карвоментон карватанацетон карвеол
Date of publication
18.09.2025
Year of publication
2025
Number of purchasers
0
Views
6

References

  1. 1. Bhatia S.P., McGinty D., Letizia C.S., Api A.M. // Food Chem. Toxicol. 2008. V. 46. № 11. P. S85–S87. https://doi.org/10.1016/j.fct.2008.06.074
  2. 2. Duetz W.A., Fjällman A.H., Ren S., Jourdat C., Witholt B. // Appl. Environ. Microbiol. 2001. V. 67. № 6. P. 2829–2832. https://doi.org/10.1128/AEM.67.6.2829-2832.2001
  3. 3. Costa V.V., da Silva Rocha K.A., de Sousa L.F., Robles-Dutenhefner P.A., Gusevskaya E.V. // J. Mol. Cat. A: Chem. 2011. V. 345. Р. 69–74. https://doi.org/10.1016/j.molcata.2011.05.020
  4. 4. de Miguel S.R, Román-Mart´ınez M.C., Cazorla-Amorós D., Jablonski E.L., Scelza O.A. // Cat. Today. 2001. V. 66. № 2–4. P. 289–295. https://doi.org/10.1016/S0920-5861 (00)00657-X
  5. 5. Chapman H.A., Herbal K., Motherwell W.B. // Synlett. 2010. V. 4. № 3. P. 595–598. https://doi.org/10.1055/s-0029-1219373
  6. 6. Stekrova M., Kumar N., Mäki-Arvela P., Ardashov O.V., Volcho K.P., Salakhutdinov N.F., Murzin D.Yu. // Materials. 2013. V. 6. № 5. P. 2103–2118. https://doi.org/10.3390/ma6052103
  7. 7. Anikeev V.I., Sivcev V.P., Il'ina I.V., Korchagina D.V., Statsenko O.B., Volcho K.P., Salakhutdinov N.F. // Russ. J. Phys. Chem. A. 2013. V. 87. № 3. P. 382–387. https://doi.org/10.7868/S0044453713030023
  8. 8. Black P.J. Catalytic electronic activation: The addition of nucleophiles to an allylic alcohol. Doctoral thesis, United Kingdom, University of Bath, 2002. 192 p.
  9. 9. Bicas J.L., Dionísio A.P., Pastore G.M. // Chem. Rev. 2009. V. 109. № 9. P. 4518–4531. https://doi.org/10.1021/cr800190y
  10. 10. Fahlbusch K.-G., Hammerschmidt F.-J., Panten J., Pickenhagen W., Schatkowski D., Bauer K., Garbe D., Surburg H. Flavors and fragrances. In: Ullmann's encyclopedia of industrial chemistry. V. 15. Elvers B., Hawkins S., Russey W. (eds.). Weinheim, Wiley-VCH Verlag GmbH & Co. KGaA, 2003. P. 73–198. https://doi.org/10.1002/14356007.a11_141
  11. 11. Demidova Y.S., Suslov E.V., Simakova O.A., Volcho K.P., Salakhutdinov N.F., Simakova I.L., Murzin D.Y. // J. Mol. Catal. A: Chem. 2016. V. 420. P. 142–148. https://doi.org/10.1016/j.molcata.2016.04.013
  12. 12. Schmidt E., Wanner J. Adulteration of essential oils. In: Handbook of essential oils: Science, technology and application. 3rd Edn. Can Baser K.H., Buchbauer G. (eds.). USA, Boca Raton, CRC Press, 2020. P. 543–580.
  13. 13. Melo C.I., Bogel-Łukasik R., Bogel-Łukasik E. // J. Supercrit. Fluids. 2012. V. 61. P. 191–198. https://doi.org/10.1016/j.supflu.2011.10.005
  14. 14. Montero G.E.R., Stassi J.P., de Miguel S.R., Zgolicz P.D. // React. Chem. Eng. 2023. V. 8. № 12. Р. 3133–3149. https://doi.org/
  15. 15. Samarov A.A., Vostrikov S.V., Glotov A.P., Verevkin S.P. // Chemistry. 2024. V. 6. № 4. P. 706–722. https://doi.org/10.3390/chemistry6040042
  16. 16. Heterogenized homogeneous catalysts for fine chemicals production: materials and processes. V. 33. Barbaro P., Liguori F. (eds.). USA: Boston, Springer, 2010. 470 p. https://doi.org/10.1007/978-90-481-3696-4
  17. 17. Benavente P., Cárdenas-Lizana F., Keane M.A. // Cat. Comm. 2017. V. 96. P. 37–40. https://doi.org/10.1016/j.catcom.2017.03.026
  18. 18. Malkar R.S., Yadav G.D. // Curr. Catal. 2020. V. 9. № 1. P. 32–58. https://doi.org/10.2174/2211544708666190613163523
  19. 19. Vilella I.M.J., de Miguel S.R., Scelza O.A. // J. Mol. Cat. A: Chem. 2008. V. 284. № 1–2. P. 161–171. https://doi.org/10.1016/j.molcata.2008.01.017
  20. 20. Gilbert L., Mercier C. Solvent effects in heterogeneous catalysis: Application to the synthesis of fine chemicals. In: Studies in surface science and catalysis. V. 78. Guisnet M. (ed.). Amsterdam, Elsevier, 1993. Р. 51. https://doi.org/10.1016/S0167-2991 (08)63303-0
  21. 21. Wehrli J.T., Baiker A., Monti D.M., Blaser H.U., Jalett H.P. // J. Mol. Cat. 1989. V. 57. № 2. P. 245–257. https://doi.org/10.1016/0304-5102 (89)80234-2
  22. 22. Augustine R.L. Advances in catalysis. V. 25. Eley D.D., Selwood P.W., Weisz P.B. (eds.). New York, Academic Press, 1976. P. 56.
  23. 23. Blaser H.U., Jalett H.P., Wiehl J. // J. Mol. Catal. 1991. V. 68. № 2. P. 215–222. https://doi.org/10.1016/0304-5102 (91)80076-F
  24. 24. Bertero N.M., Trasarti A.F., Apesteguía C.R., Marchi A. // J. App. Catal. A: Gen. 2011. V. 394. № 1–2. P. 228–238. https://doi.org/10.1016/j.apcata.2011.01.003
  25. 25. Li M., Wang X., Cárdenas-Lizana F., Keane M.A. // Catal. Today. 2017. V. 279. № 1. P. 19–28. https://doi.org/10.1016/j.cattod.2016.06.030
  26. 26. Cárdenas-Lizana F., Lamey D., Gómez-Quero S., Perret N., Kiwi-Minsker L., Keane M.A. // Catal. Today. 2011. V. 173. № l. P. 53–61. https://doi.org/10.1016/j.cattod.2011.03.084
  27. 27. Cárdenas-Lizana F., Hao Y., Crespo-Quesada M., Yuranov I., Wang X., Keane M.A., Kiwi-Minsker L. // ACS Catal. 2013. V. 3. № 6. P. 1386–1396. https://doi.org/10.1021/cs400194
  28. 28. Petrier C., Luche J.-L. // Tetrahedron lett. 1987. V. 28. № 21. P. 2351–2352. https://doi.org/10.1016/S0040-4039 (00)96120-3
  29. 29. Li M., Hao Y., Cárdenas-Lizana F., Yiu H.H.P., Keane M.A. // Top. Catal. 2015. V. 58. P. 149–158. https://doi.org/10.1007/s11244-014-0354-9
  30. 30. Molnar A., Sarkany A., Varga M. // J. Mol. Catal. A: Chem. 2001. V. 173. № 1. P. 185–221. https://doi.org/10.1016/S1381-1169 (01)00150-9
  31. 31. Shorthouse L.J., Roberts A.J., Raval R. // Surf. Sci. 2001. V. 480. № 1–2. P. 37–46. https://doi.org/10.1016/S0039-6028 (01)00991-8
  32. 32. Brunner E. // J. Chem. Eng. Data. 1985. V. 30. № 3. P. 269–273. https://doi.org/10.1021/je00041a010
  33. 33. Saboktakin M.R., Tabatabaie R.M., Maharramov A., Ramazanov M.A. // Synth. Comm. 2011. V. 41. № 10. P. 1455–1463. https://doi.org/10.1080/00397911.2010.486510
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