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RAS PresidiumДоклады Российской академии наук. Химия, науки о материалах Doklady Chemistry

  • ISSN (Print) 2686-9535
  • ISSN (Online) 3034-5111

TRANSITION METAL-FREE ACETYLENE CHEMISTRY: TRENDS AND RATES OF DEVELOPMENT. A REVIEW

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PII
S3034511125020017-1
DOI
10.7868/S3034511125020017
Publication type
Review
Status
Published
Authors
B. A. Trofimov
  • Affiliation: Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Volume/ Edition
Volume 521 / Issue number 1
Pages
3-14
Abstract
Behind the modern snowballing growth of publications devoted to transition metal-catalyzed chemistry of acetylene, the works dealing with acid- and base-promoted acetylene reactions stand in the background, although acid-base catalysis, along with enzymatic one, hold a dominant place in living nature. It was acid-base catalysis that was historically first introduced into human practice, and then into research. Until now, the majority of practically important reactions involving acetylene (these are mainly Favorsky reactions: vinylation of alcohols, ethynylation of carbonyl compounds, prototropic isomerization of alkynes, rearrangement of α-haloketones) represent base-catalyzed processes. Over the last decades, transition metal-free acetylene chemistry was progressing owing to the employment of superbases and superacids for the activation of the triple carbon-carbon bond. In the present paper, using recent publications of the authors (2021), the advances in application of superbase media in the chemistry of alkynes are surveyed. Also, the usage of electron-deficient acetylenes as objects especially sensitive to the action of bases in the search for new preparative reactions with participation of the triple carbon-carbon bond is analyzed. A short period (one year) was chosen in order to clearly illustrate the dynamics and efficiency of research in this area.
Keywords
ацетилен супероснования органический синтез гетероциклические соединения
Date of publication
02.04.2025
Year of publication
2025
Number of purchasers
0
Views
4

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