- PII
- S3034511125060078-1
- DOI
- 10.7868/S3034511125060078
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 525 / Issue number 1
- Pages
- 81-92
- Abstract
- The results of the kinetic studies of the influence of reaction system components on the composition of truly active Pd complexes participating in the formation of bicyclo[2.2.1]heptane derivatives as a result of three-component coupling of aryl halide, norbornene, and aryl acetylene are discussed. Based on the data on the sensitivity of differential selectivity of conjugation nodes of competing catalytic cycles of the reaction under consideration the anionic character and mixed-ligand composition of catalytically active Pd compounds have been established.
- Keywords
- норборнен производные бицикло[2.2.1]гептана катализ палладий кинетика дифференциальная селективность
- Date of publication
- 01.01.2026
- Year of publication
- 2026
- Number of purchasers
- 0
- Views
- 42
References
- 1. Shi Y., Ji C. L., Liu C. J. Org. Chem. 2023. V. 88. P. 261–271. https://doi.org/10.1021/acs.joc.2c02295
- 2. Xu T., Zhou X., Han Y., Zhang L., Liu L., Huang T., Li C., Tang Z., Wan S., Chen T. Tetrahedron Lett. 2022. V. 97. Article 153799. https://doi.org/10.1016/j.tetlet.2022.153799
- 3. Pounder A., Neufeld E., Myler P., Tam W. Beilstein J. Org. Chem. 2023. V. 19. P. 487–540. https://doi.org/10.3762/bjoc.19.38
- 4. Pajić M., Barišić D., Babić D., Ćurić M., Juribašić Kulcsár M. Chem. Methods 2024. V. 5. Article e202400025. https://doi.org/10.1002/cmtd.202400025
- 5. Olding A., Ho C. C., Maiti D., Bissember A. Chem. Commun. 2023. V. 59. P. 5144–5155. https://doi.org/10.1039/D3CC00882G
- 6. Schroeter F., Strassner T. Inorg. Chem. 2018. V. 57. P. 5159–5173. https://doi.org/10.1021/acs.inorgchem.8b00175
- 7. Темкин О.Н. Кинетика и катализ. 2012. Т. 53. № 3. С. 326–357.
- 8. Prima D.O., Vatsadze S.Z. Organometallics. 2025. V. 44. P. 1337–1357. https://doi.org/10.1021/acs.organomet.5c00117
- 9. Amatore C., Jutand A. Acc. Chem. Res. 2000. V. 33. № 5. P. 314–321. https://doi.org/10.1021/ar980063a
- 10. Carrow B.P., Hartwig J.F. J. Am. Chem. Soc. 2010. V. 132. № 1. P. 79–81. https://doi.org/10.1021/ja909306f
- 11. Larina E.V., Kurokhtina A.A., Vidyaeva E.V., Lagoda N.A., Schmidt A.F. Mol. Catal. 2021. V. 513. Article 111778. https://doi.org/10.1016/j.mcat.2021.111778
- 12. Eremin D.B., Denisova E.A., Kostyukovich A.Yu., Martens J., Berden G., Oomens J., Khrustalev V.N., Chernyshev V.M., Ananikov V.P. Chem. Eur. J. 2019. V. 25. № 72. P. 16564–16572. https://doi.org/10.1002/chem.201903221
- 13. Kohlmann J., Braun T. J. Fluor. Chem. 2017. V. 203. P. 140–145. https://doi.org/10.1016/j.jfluchem.2017.08.003
- 14. Jutand A. Eur. J. Inorg. Chem. 2003. V. 2003. № 11. P. 2017–2040. https://doi.org/10.1002/ejic.200300069
- 15. Schmidt A.F., Kurokhtina A.A., Larina E.V. Cat. Sci. Technol. 2014. V. 4. № 10. P. 3439–3457. https://doi.org/10.1039/c4cy00479e
- 16. Шмидт А.Ф., Курохтина А.А., Ларина Е.В. Кинетика и катализ. 2019. Т. 60. № 5. С. 555–577. https://doi.org/10.1134/S0453881119050113
- 17. García-Melchor M., Pacheco M.C., Nájera C., Lledós A., Ujaque G. ACS Catal. 2012. V. 2. № 1. P. 135–144. https://doi.org/10.1021/cs200526x
- 18. Larina E.V., Lagoda N.A., Kurokhtina A.A., Schmidt A.F. Russ. J. Org. Chem. 2025. V. 61. № 4. P. 647–654. https://doi.org/10.1134/S1070428025601050
- 19. Carrow B.P., Hartwig J.F. J. Am. Chem. Soc. 2011. V. 133. № 7. P. 2116–2119. https://doi.org/10.1021/ja1108326
- 20. Schmidt A.F., Kurokhtina A.A., Larina E.V., Yarosh E.V., Lagoda N.A. Organometallics. 2017. V. 36. № 17. P. 3382–3386. https://doi.org/10.1021/acs.organomet.7b00496
- 21. Митчелл Д., Смит Д. Акваметрия. Шерман Ф.Б. (ред.) М.: Химия, 1980. 600 с.
- 22. Billo E.J. Excel for scientists and engineers: Numerical methods. 2nd edn. John Wiley & Sons, 2007. 480 р.