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RAS PresidiumДоклады Российской академии наук. Химия, науки о материалах Doklady Chemistry

  • ISSN (Print) 2686-9535
  • ISSN (Online) 3034-5111

MAGNETOSENSITIVE LUMINESCENCE OF RECOMBINATION EXCIPLEXES OF DIMETHYL AND DIMETHOXY TOLAN WITH N,N-DIMETHYLANILINE GENERATED BY X-IRRADIATION IN NONPOLAR SOLUTION

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PII
S30345111S2686953525030068-1
DOI
10.7868/S3034511125030068
Publication type
Article
Status
Published
Authors
D. V. Stass
  • Affiliation:
    V.V. Voevodsky Institute of Chemical Kinetics and Combustion of Siberian Branch of Russian Academy of Sciences
    Novosibirsk State University
V. N. Verkhovlyuk
  • Affiliation: HUN-REN Wigner Research Centre for Physics
A. A. Stepanov
  • Affiliation: V.V. Voevodsky Institute of Chemical Kinetics and Combustion of Siberian Branch of Russian Academy of Sciences
S. F. Vasilevsky
  • Affiliation: V.V. Voevodsky Institute of Chemical Kinetics and Combustion of Siberian Branch of Russian Academy of Sciences
Volume/ Edition
Volume 522 / Issue number 1
Pages
42-50
Abstract
On the example of three compounds it is demonstrated that upon X-irradiation in nonpolar solution donor-substituted dimethyl- and dimethoxy-(diphenylacetylenes) form exciplexes with N,N-dimethylaniline via recombination of the respective radical ions with an intense magnetosensitive band of luminescence. Exciplexes of dimethyldiphenylacetylenes have the highest light production of all recombination exciplexes of diphenylacetylenes known so far. The studied compounds and their analogs as a class may be considered as potential blue emitters for organic electroluminescent systems, including magnetosensitive ones.
Keywords
люминесценция эксиплекс дифенилацетилен рекомбинация ион-радикальных пар магнитный эффект органический светодиод
Date of publication
01.06.2025
Year of publication
2025
Number of purchasers
0
Views
18

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